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Allyl(chloro)[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(II)
Description
The derivative of this compound serves as an exceptionally mild and versatile catalyst for Heck reactions of aryl chlorides and bromides. A sterically and electronically diverse array of aryl bromides, as well as activated aryl chlorides, couple with a range of mono- and disubstituted olefins at room temperature, furnishing the arylated product with high E/Z stereoselection.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Spécification
Spécification
| CAS | 1235509-04-2 |
| Color | Yellow |
| Molecular Formula | C19H33ClNPPd |
| MDL Number | MFCD25372543 |
| Quantity | 1 g |
| Synonym | pdclallyl amphos, allyl chloro di-tert-butyl 4-dimethylaminophenyl phosphine palladium ii |
| Solubility Information | Insoluble in water. |
| InChI Key | OSTWSTKYPFRHAA-UHFFFAOYSA-M |
| SMILES | CC(C)(C)P(C1=CC=C(C=C1)CNC)C(C)(C)C.[CH2-]C=C.Cl[Pd+] |
| IUPAC Name | chloropalladium(1+);1-(4-ditert-butylphosphanylphenyl)-N-methylmethanamine;prop-1-ene |
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RUO – Research Use Only
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