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  6. Dodecacarbonyltriruthenium, 99%

Dodecacarbonyltriruthenium, 99%

Product Code. 11316008
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Product Code. 11316008 Supplier Thermo Scientific Alfa Aesar Supplier No. 010507.03
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Description

Carbonylation | CAS: 15243-33-1 | C12O12Ru3 | 639.33 g/mol

A H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF).

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 15243-33-1
Molecular Formula C12O12Ru3
Molecular Weight (g/mol) 639.33
MDL Number MFCD00011209
InChI Key NQZFAUXPNWSLBI-UHFFFAOYSA-N
Synonym Ruthenium carbonyl; Triruthenium dodecacarbonyl
IUPAC Name cyclotriruthenium; dodecakis(methanidylidyneoxidanium)
SMILES [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Ru]1[Ru][Ru]1

Specifications

Melting Point ∼150°C (decomposition)
Color Orange
Linear Formula Ru3(CO)12
Quantity 1 g
UN Number UN3466
Solubility Information Sparingly soluble in hydrocarbons (e;g; hexane,cyclohexane,benzene) and acetone.
Formula Weight 639.33
Percent Purity 99%
Physical Form Crystalline
Chemical Name or Material Dodecacarbonyltriruthenium

RUO – Research Use Only

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