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m-Anisidine, 98%

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CAS: 536-90-3 | C7H9NO | 123.155 g/mol

The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.

Solubility
Soluble in water(18g/L).

Notes
Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Identificatori chimici

CAS 536-90-3
Molecular Formula C7H9NO
Molecular Weight (g/mol) 123.155
MDL Number MFCD00007783
InChI Key NCBZRJODKRCREW-UHFFFAOYSA-N
Synonym m-anisidine, 3-aminoanisole, m-methoxyaniline, 3-methoxybenzenamine, 3-anisidine, m-aminoanisole, benzenamine, 3-methoxy, m-anisylamine, 1-amino-3-methoxybenzene, unii-jxa144kx2i
PubChem CID 10824
IUPAC Name 3-methoxyaniline
SMILES COC1=CC=CC(=C1)N

Specifica

Melting Point -1°C
Density 1.101
Boiling Point 250°C to 251°C
Flash Point 126°C (258°F)
Odor Characteristic
Refractive Index 1.581
Quantity 250 g
UN Number UN2431
Beilstein 386119
Sensitivity Light sensitive
Merck Index 14,667
Solubility Information Soluble in water(18g/L).
Formula Weight 123.16
Percent Purity 98%
Chemical Name or Material m-Anisidine
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Identificativo prodotto
  • m-Anisidine
Avvertenza
  • Danger
Categoria di pericolo
  • Acute toxicity Category 3
  • Acute toxicity Category 4
  • LONG-TERM AQUATIC HAZARD Chronic 1
  • ACUTE AQUATIC Acute 1
  • Specific target organ toxicity after repeated exposure Category 2
Indicazioni di pericolo
  • H302-Harmful if swallowed.
  • H311-Toxic in contact with skin.
  • H332-Harmful if inhaled.
  • H373-May cause damage to organs.
  • H400-Very toxic to aquatic life.
  • H410-Very toxic to aquatic life with long lasting effects.
Consigli di prudenza
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
  • P302+P352-IF ON SKIN: Wash with plenty of water/soap.
  • P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P312-Call a POISON CENTER/doctor/if you feel unwell.
Informazioni supplementari
  • MIXTURE LIST-Contain: m-Anisidine

RUO – Research Use Only

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