missing translation for 'onlineSavingsMsg'
Learn More
  1. Home
  2. Products
  3. Chemicals
  4. Organic compounds
  5. Benzenoids
  6. Benzene and substituted derivatives
  7. Phenylphosphines and derivatives
  8. (Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+%

(Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+%

Product Code. 11467767
Change view
Click to view available options
Quantity:
25 g
100 g
500 g
Unit Size:
100g
25g
500g
3 product options available for selection
Product selection table with 3 available options. Use arrow keys to navigate and Enter or Space to select.
Product Code. Quantity unitSize
11467767 100 g 100g
11457767 25 g 25g
11477767 500 g 500g
Use arrow keys to navigate between rows. Press Enter or Space to select a product option. 3 options available.
3 options
This item is not returnable. View return policy
Product Code. 11467767 Supplier Thermo Scientific Alfa Aesar Supplier No. A16301.22
Request Bulk or Custom Format

Please to purchase this item. Need a web account? Register with us today!

This item is not returnable. View return policy

Description

CAS: 1779-58-4 | C21H20BrO2P | 415.27 g/mol

(Methoxycarbonylmethyl)triphenylphosphonium bromide is a reactant for the synthesis of GSK-3 inhibitors using the Wittig reaction, substituted furanones for antifungal and cytostatic activities, photochromic dithienylethene derivatives, gem-diiodoalkanes containing allylic alcohols and highly substituted cyclopentenes and brazilanes via Au-catalyzed deoxygenative Nazarov cyclization. As reactant for asymmetric hydrogenation of α,β-unsaturated ester-phosphonates, studies of thermal decomposition of phosphonium alkyl ester salts.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(Methoxycarbonylmethyl)triphenylphosphonium bromide is a reactant for the synthesis of GSK-3 inhibitors using the Wittig reaction, substituted furanones for antifungal and cytostatic activities, photochromic dithienylethene derivatives, gem-diiodoalkanes containing allylic alcohols and highly substituted cyclopentenes and brazilanes via Au-catalyzed deoxygenative Nazarov cyclization. As reactant for asymmetric hydrogenation of α,β-unsaturated ester-phosphonates, studies of thermal decomposition of phosphonium alkyl ester salts.

Solubility
Soluble in methanol(almost transparency).

Notes
Hygroscopic. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 1779-58-4
Molecular Formula C21H20BrO2P
Molecular Weight (g/mol) 415.27
MDL Number MFCD00011801
InChI Key VCWBQLMDSMSVRL-UHFFFAOYSA-M
Synonym 2-methoxy-2-oxoethyl triphenylphosphonium bromide, methoxycarbonylmethyl triphenylphosphonium bromide, carbomethoxymethyl triphenylphosphonium bromide, methoxycarbonylmethyl triphenyl phosphonium bromide, 2-methoxy-2-oxoethyl triphenylphosphanium bromide, 2-methoxy-2-oxoethyl-triphenylphosphanium bromide, 2-methoxy-2-oxo-ethyl-triphenyl-phosphonium bromide, phosphonium, 2-methoxy-2-oxoethyl triphenyl-, bromide, acmc-209edx
PubChem CID 2733211
IUPAC Name (2-methoxy-2-oxoethyl)-triphenylphosphanium;bromide
SMILES [Br-].COC(=O)C[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1

Specifications

Melting Point ∼163°C (decomposition)
Quantity 100 g
Beilstein 3812975
Sensitivity Hygroscopic
Solubility Information Soluble in methanol(almost transparency).
Formula Weight 415.28
Percent Purity ≥98%
Chemical Name or Material (Methoxycarbonylmethyl)triphenylphosphonium bromide

RUO – Research Use Only

Product Title
Select an issue

By clicking Submit, you acknowledge that you may be contacted by Fisher Scientific in regards to the feedback you have provided in this form. We will not share your information for any other purposes. All contact information provided shall also be maintained in accordance with our Privacy Policy.