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Tebbe reagent, 0.5M solution in toluene, Thermo Scientific Chemicals
Brand: Thermo Scientific Acros 368971000
Additional Details : CAS : 67719-69-1 Weight : 0.09270kg Transport : UN number : 2924 Chem class : 3 Pack group : II
Description
This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
For C-C Bond Formation (Olefination), Lewis acidSpecifications
| Tebbe reagent | |
| 67719-69-1,108-88-3 | |
| 0.9270g/mL | |
| AcroSeal™ Glass bottle | |
| MFCD00151575 | |
| 08,83; 10,87; 11,52; 12,54; 13,71; 15,79; 16,70; 17,69 | |
| Bis(cyclopentadienyl-μ-chloro(dimethylaluminum-μ-methylenetitanium | |
| 284.62 |
| 0.5M solution in toluene | |
| Purple to Red | |
| 4°C | |
| C13H18AlClTi | |
| 100 mL | |
| 0.927 | |
| Solubility in water: reacts. | |
| Solution |
Safety and Handling
Product Identifier
Signal Word
Hazard Category
Hazard Statement
Precautionary Statement
- Tebbe reagent, 0.5M solution in toluene
Signal Word
- Danger
Hazard Category
- Aspiration toxicity Category 1
- Serious eye damage/eye irritation Category 1
- Flammable liquid Category 2
- Reproductive toxicity Category 2
- Skin corrosion/irritation Category 1 B
- Specific target organ toxicity after repeated exposure Category 2
- Specific target organ toxicity Category 3
Hazard Statement
- H304-May be fatal if swallowed and enters airways.
- H318-Causes serious eye damage.
- H314-Causes severe skin burns and eye damage.
- H361-Suspected of damaging fertility or the unborn child.
- H373-May cause damage to organs.
- H336-May cause drowsiness or dizziness.
- H225-Highly flammable liquid and vapour.
Precautionary Statement
- P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
- P240-Ground/bond container and receiving equipment.
- P260-Do not breathe dust/fume/gas/mist/vapours/spray.
- P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
- P280-Wear protective gloves/protective clothing/eye protection/face protection.
- P301+P310-IF SWALLOWED: Immediately call a POISON CENTER/doctor /
- P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P310-Immediately call a POISON CENTER/doctor/.
- P331-Do NOT induce vomiting.
RUO – Research Use Only