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  7. cis-2-Butene-1,4-diol, 96%, remainder trans-isomer

cis-2-Butene-1,4-diol, 96%, remainder trans-isomer

Product Code. 11499456
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Product Code. 11499456 Supplier Thermo Scientific Alfa Aesar Supplier No. A19182.30
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Description

CAS: 6117-80-2 | C4H8O2 | 88.11 g/mol

cis-2-Butene-1, 4-diol is used as a probe for studying isomerization versus hydrogenation and hydrogenolysis reactions. (DPCB-OMe) efficiently catalyzes cyclodehydration of cis-2-butene-1,4-diol with active methylene compounds to give 2-vinyl-2,3-dihydrofurans in good to high yields. Grubbs's cross metathesis of eugenol with cis-2-butene-1, 4-diol to make a natural product, an organometallic experiment.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
cis-2-Butene-1, 4-diol is used as a probe for studying isomerization versus hydrogenation and hydrogenolysis reactions. (DPCB-OMe) efficiently catalyzes cyclodehydration of cis-2-butene-1,4-diol with active methylene compounds to give 2-vinyl-2,3-dihydrofurans in good to high yields. Grubbs′s cross metathesis of eugenol with cis-2-butene-1, 4-diol to make a natural product, an organometallic experiment.

Solubility
Soluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 6117-80-2
Molecular Formula C4H8O2
Molecular Weight (g/mol) 88.11
MDL Number MFCD00002924,MFCD00063207
InChI Key ORTVZLZNOYNASJ-UPHRSURJSA-N
Synonym cis-2-butene-1,4-diol, z-2-butene-1,4-diol, cis-butenediol, unii-za7vgu6scv, cis-1,4-dihydroxy-2-butene, z-but-2-ene-1,4-diol, 2-butene-1,4-diol, 2z-but-2-ene-1,4-diol, 2-butene-1,4-diol, z, za7vgu6scv
PubChem CID 643790
IUPAC Name (Z)-but-2-ene-1,4-diol
SMILES OC\C=C/CO

Specifications

Melting Point 6°C to 8°C
Density 1.07
Boiling Point 131°C to 132°C (12 mmHg)
Flash Point 127°C (260°F)
Refractive Index 1.478
Quantity 250 g
Beilstein 1679241
Solubility Information Soluble in water.
Formula Weight 88.11
Percent Purity 96%
Assay remainder trans-isomer
Chemical Name or Material cis-2-Butene-1,4-diol
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Safety and Handling

compliance-icons
Product Identifier
  • cis-2-Butene-1,4-diol
 Signal Word
  • Warning
 Hazard Category
  • Acute toxicity Category 4
  • Serious eye damage/eye irritation Category 2
  • Skin corrosion/irritation Category 2
  • Specific target organ toxicity Category 3
 Hazard Statement
  • H302-Harmful if swallowed.
  • H315-Causes skin irritation.
  • H319-Causes serious eye irritation.
  • H335-May cause respiratory irritation.
 Precautionary Statement
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P312-IF SWALLOWED: Call a POISON CENTER or doctor/physician/ if you feel unwell.
  • P302+P352-IF ON SKIN: Wash with plenty of water/soap.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P332+P313-If skin irritation occurs: Get medical advice/attention.
  • P337+P313-If eye irritation persists: Get medical advice/attention.
 Supplemental information
  • MIXTURE LIST-Contains : (Z)-2-Butene-1,4-diol
SDS

RUO – Research Use Only

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